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101.
Hao Yuan Haifeng Dai Wei Wu Jiaping Xie Jun Shen Xuezhe Wei 《International Journal of Hydrogen Energy》2021,46(7):5714-5728
In a vehicular fuel cell system, alternative load and frequent purge action can lead to anode pressure varies with the hydrogen mass flow fluctuation. It's crucial to control the pressure difference between anode and cathode within a reasonable range to avoid adverse phenomena such as membrane failure, reactant starvation, or even water management fault. In this paper, an improved proportional integrative (PI) controller by the fuzzy logic technique that considers the engineer experience and knowledge on the hydrogen supply system behavior is proposed for hydrogen pressure control, in which the PI parameters are tuned by a fuzzy decision process. Furthermore, load current and purge action regarded as input disturbances are applied for feedforward compensation to reduce the pressure response hysteresis. A hydrogen supply subsystem based on the proportional valve is modeled, and corresponding parameters are determined by analyzing the response time and steady pressure fluctuation. The performance of the conventional PI controller, the fuzzy logic PI (FLPI) controller and fuzzy logic PI with feedforward (FLPIF) controller is validated. The presented results indicated that the FLPI controller significantly improves the dynamic response of hydrogen pressure compared to the PI controller, and the FLPIF controller can further reduce overshoot caused by disturbance. Finally, the proposed FLPIF controller is implemented on a rapid prototype platform of the hydrogen supply subsystem and an actual fuel cell system, exhibiting satisfactory performance. 相似文献
102.
Biyun Fang Chuanfeng Zhang Zeliang Qi Chunyan Li Jun Ni Xiuyun Wang Jianxin Lin Chak-Tong Au Bingyu Lin Lilong Jiang 《American Institute of Chemical Engineers》2022,68(11):e17849
The design of an efficient non-noble metal catalyst is of burgeoning interest for ammonia synthesis. Herein, we report a Mo2C/CeO2 catalyst that is superior in ammonia synthesis activity. In this catalyst, molybdenum carbide coexisted with the ceria overlayers which is from the ceria support as the strong metal–support interaction. There is a high proportion of low-valent Mo species, as well as high concentration of Ce3+ and surface oxygen species. The presence of Mo2C and CeO2 overlayers not only leads to enhancement of hydrogen and nitrogen adsorption, but also facilitates the desorption and exchange of adsorbed species with the gaseous reagents. Compared with the Mo/CeO2 catalyst prepared without carbonization, the Mo2C/CeO2 catalyst is more than sevenfold higher in ammonia synthesis rate. This work not only presents an explicit example of designing Mo-based catalyst that is highly efficient for ammonia synthesis by tuning the adsorption and desorption properties of the reactant gases, but opens a perspective for other elements in ammonia synthesis. 相似文献
103.
Effective distribution coefficients of 9 impurities in 1,2-diphenylethane have been calculated by directional crystallization under different ambient frozen temperature. The effect of varied zone size, temperature difference between the melt and ambient frozen environment, number of zone on purity of 1,2-diphenylethane have been also investigated during the process of zone refining. The results indicate that the product purity in the intermediate purified region with varied zone size is higher 0.04%-0.2% than that with constant zone size. The product purity increases with temperature difference between the melt and ambient frozen environment. The appropriate temperature difference is adopted 50℃. The product purity in the intermediate region of sample bar with 2 molten zones is higher 0.05%-0.43% than that with 1 molten zone. In addition, the change of enthalpy and entropy between impurities and 1,2-diphenylethane have been determined. 相似文献
105.
Photothermal therapy (PTT) mediated by nanomaterial has become an attractive tumor treatment method due to its obvious advantages. Among various nanomaterials, melanin-like nanoparticles with nature biocompatibility and photothermal conversion properties have attracted more and more attention. Melanin is a natural biological macromolecule widely distributed in the body and displays many fascinating physicochemical properties such as excellent biocompatibility and prominent photothermal conversion ability. Due to the similar properties, Melanin-like nanoparticles have been extensively studied and become promising candidates for clinical application. In this review, we give a comprehensive introduction to the recent advancements of melanin-like nanoparticles in the field of photothermal therapy in the past decade. In this review, the synthesis pathway, internal mechanism and basic physical and chemical properties of melanin-like nanomaterials are systematically classified and evaluated. It also summarizes the application of melanin-like nanoparticles in bioimaging and tumor photothermal therapy (PTT)in detail and discussed the challenges they faced in clinical translation rationally. Overall, melanin-like nanoparticles still have significant room for development in the field of biomedicine and are expected to applied in clinical PTT in the future. 相似文献
106.
107.
Lin Chen Jun Guo Yuke Zhu Mingyu Hu Jing Feng 《Journal of the American Ceramic Society》2021,104(1):404-412
The features of crystal structures, thermo-mechanical properties and their dominant mechanisms of weberites RE3NbO7 were studied as high-temperature oxides. We concentrated on connections between structures and thermo-mechanical properties, the influences of bond lengths, lattice distortion degrees and microstructures on these properties were estimated. The shortening of bond length and increment of bonding strength would lead to the increase of mechanical properties. The Vickers hardness (4.5-7.8 GPa) and toughness (0.5-1.6 MPa·m1/2) of weberites RE3NbO7 are enhanced by grain refinement and increment of bond strength, while crystal structures, bond lengths, and lattice distortion degrees influenced their Young's modulus (100-170 GPa). Nano-indentation was applied to test the influence of microstructures on modulus and hardness. The dominant mechanisms for mechanical properties and thermal conductivity were proposed, which was conducive to properties tailoring and engineering applications of weberites RE3NbO7 oxides. 相似文献
108.
Jun Wang Fushuo Wu Ruoan Zou Yueshu Wu Mengdi Gan Jing Feng Xiaoyu Chong 《Journal of the American Ceramic Society》2021,104(11):5873-5882
In this study, high-entropy rare-earth tantalate ceramics (Y0.2Ce0.2Sm0.2Gd0.2Dy0.2)TaO4 ((5RE0.2)TaO4) have been successfully fabricated. The possibility of formation of (5RE0.2)TaO4 was verified via first-principles calculations. In addition, the phase structure, ferroelastic toughening mechanism, thermophysical, and mechanical properties were systematically investigated. The (5RE0.2)TaO4 ceramics have lower phonon thermal conductivity (1.2–2.6 W·m–1·K–1) in the entire temperature range than that of RETaO4 and YSZ. (5RE0.2)TaO4 has a higher fracture toughness and lower brittleness index than YSZ. The thermal expansion coefficients of (5RE0.2)TaO4 are as high as 10.3 × 10-6 K–1 at 1200°C and Young's modulus is 66–189 GPa, and thus, (5RE0.2)TaO4 possesses great potential for application in thermal barrier coatings (TBCs). 相似文献
109.
Kana Asano-Matsuda Sajida Ibrahim Tomoko Takano Jun Matsuda 《International journal of molecular sciences》2021,22(7)
The first step of urine formation is the selective filtration of the plasma into the urinary space at the kidney structure called the glomerulus. The filtration barrier of the glomerulus allows blood cells and large proteins such as albumin to be retained while eliminating the waste products of the body. The filtration barrier consists of three layers: fenestrated endothelial cells, glomerular basement membrane, and podocytes. Podocytes are specialized epithelial cells featured by numerous, actin-based projections called foot processes. Proteins on the foot process membrane are connected to the well-organized intracellular actin network. The Rho family of small GTPases (Rho GTPases) act as intracellular molecular switches. They tightly regulate actin dynamics and subsequent diverse cellular functions such as adhesion, migration, and spreading. Previous studies using podocyte-specific transgenic or knockout animal models have established that Rho GTPases are crucial for the podocyte health and barrier function. However, little attention has been paid regarding subcellular locations where distinct Rho GTPases contribute to specific functions. In the current review, we discuss cellular events involving the prototypical Rho GTPases (RhoA, Rac1, and Cdc42) in podocytes, with particular focus on the subcellular compartments where the signaling events occur. We also provide our synthesized views of the current understanding and propose future research directions. 相似文献
110.